Controllable fabrication of micro/nanostructures by electrospinning from polystyrene/poly(vinyl alcohol) emulsion dispersions

In this article, controllable micro/nanostructures were successfully obtained by electrospinning with the emulsion dispersions of polystyrene and poly(vinyl alcohol) (PS/PVA). The micro/nanostructure of electrospun PS/PVA emulsion dispersions such as corn‐like, spindle‐like, and bowl‐like (or bracelet‐like) were precisely controlled by regulating the electrospun parameters including the surfactant, the applied voltages, and the compositions of PS/PVA emulsion dispersions. The non‐ionic surfactant (Poloxamer) was crucial for the stability of the PS/PVA emulsion dispersions although the surfactant in PS/PVA emulsion was in tiny amount. The high applied voltages were beneficial for the forming the “lined‐fiber” structure but not for spheroids structure (bracelet‐like structure). Moreover, the increasing content of PS in PS/PVA emulsion resulted in more spheroid structure than the “lined‐fiber.” This work was meaningful for the forming mechanism of micro/nanostructure in emulsion electrospinning and made a potential contribution for controllable fabrication of micro/nanostructure of the electrospun PS/PVA emulsion dispersions. © 2018 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2018 , 135, 46288.     

利用蒸发法和机械合金化法制备纳米Fe-Al金属间化合物

利用两种方法制备了纳米Fe-Al金属间化合物:一种是利用氢电弧等离子体法在自制的设备中以Fe-28Al-5Cr块体材料为原料,利用电弧高温蒸发制备出纳米Fe-Al基金属间化合物,该方法制得的纳米粒子呈球形,平均粒度30 nm,为B2相结构。在600℃真空退火1 h后,纳米粒子发生了B2→DO3相转变;第二种是利用机械合金化方法,将氢电弧等离子体法制备的纳米金属铁、铝单质置于球磨罐中混合湿磨,发现湿磨10 h形成了Fe-Al金属间化合物。     

机械加工法实现金属材料表面自身纳米化的研究进展

综述了机械加工法实现金属材料表面自身纳米化的研究现状,分别从制备方法、纳米化层的形成机制、纳米化层的特点和性能等方面的研究进展进行了阐述,并对表面自身纳米化技术的发展趋势进行了简单的分析.     

热障涂层的研究现状与发展方向

热障涂层(TBCs)是目前最先进的高温防护涂层之一,具有良好的隔热效果和抗高温氧化性能.综述了热障涂层的陶瓷材料、粘结层材料、涂层结构、制备工艺及涂层失效机理等5个方面的研究现状,在此基础上提出了热障涂层的发展方向.     

纳米晶材料的制备、结构性能及其进展

纳米晶材料（ｎａｎｏｓｔｒｕｃｔｕｒｅｄｍａｔｅｒｉａｌｓ）是近来发展起来的一种新型材料，其单个晶粒尺寸为纳米级，构成了一种与晶态和非晶态均不相同的新型结构，由此产生了许多独特的性能．本文综述了纳米晶材料的研究动态、介绍了纳米晶材料的制备、结构表征和性能研究的进展及纳米晶材料的发展动向。     

梯度热障涂层热冲击性能研究

采用等离子喷涂的方法,分别获得了２ｍｍ ＺｒＯ２－ＮｉＣｒＡｌ和ＺｒＯ２－Ｎｉ／Ａｌ系梯度热障涂层。热冲击实验结果表明,两种涂层具有不同的失效机理。ＺｒＯ２－ＮｉＣｒＡｌ系的失效是由于基于基体氧化引起的涂层整体脱落;而ＺｒＯ２－Ｎｉ／Ａｌ系的失效是支径向裂纹扩展到Ｎｉ／Ａｌ底层氧化共同作用的结果。     

Textures in nanostructured metals processed by severe plastic deformation

This work demonstrates and analyzes the experimental results of the crystallographic texture formation processes in pure metals with a different type of crystal lattice, which were subjected to severe plastic deformation (SPD) applying various techniques such as high pressure torsion (HPT) and equal-channel angular pressing (ECAP). This article is based on a presentation made in “ICOTOM-13: Textures of Materials” held at Seoul National University, Seoul, Korea, August 26–30, 2002, organized by The Korean Institute of Metals and Materials BK21 Division of Materials Education and Research (Seoul National University) and Texture Control Laboratory (Seoul National University).     

Study of Multi-Function Micro-Plasma Spraying Technology

A multi-functional micro-arc plasma spraying system was developed according to aerodynamics and plasma spray theory. The soft switch IGBT （Insulated Gate Bipolar Transistor） invert technique, micro-computer control technique, convergent-divergent nozzle structure and axial powder feeding techniques have been adopted in the design of the micro-arc plasma spraying system. It is not only characterized by a small volume, a light weight, highly accurate control, high deposition efficiency and high reliability, but also has multi-functions in plasma spraying, welding and quenching. The experimental results showed that the system can produce a supersonic flame at a low power, spray Al2O3 particles at an average speed up to 430 m/s, and make nanostructured AT13 coatings with an average bonding strength of 42.7 MPa. Compared to conventional 9M plasma spraying with a higher power, the coatings with almost the same properties as those by conventional plasma spray can be deposited by multi-functional micro-arc plasma spraying with a lower power plasma arc due to an improved power supply design, spray gun structure and powder feeding method. Moreover, this system is suitable for working with thin parts and undertaking on site repairs, and as a result, the application of plasma spraying will be greatly extended.     

Microstructure and Properties of Al-6061 Alloy by Equal Channel Angular Extrusion for 16 Passes

The experimental researches on Equal Channel Angular Extrusion (ECAE) process of commercial available Al-6061 alloy were conducted and the grain refinement after ECAE processing was investigated. Sixteen passes of ECAE processing at room temperature were conducted and the relationship of grain refinement with extrusion pass was established. The property enhancements after ECAE processing including ultimate tensile strength and Vickers microhardness were investigated to determine the effects of the number of ECAE passes on the mechanical properties of the extruded samples. The research presents a whole picture of ECAE processing of the alloy for up to 16 passes.